Barium Fluoride
OVERVIEW
Barium Fluoride can be used in the ultraviolet,
visible and infrared spectral regions. Barium fluoride is commonly
used in cryogenically cooled thermal imaging systems. Barium fluoride
windows can be found in infrared spectroscopy applications (ex. in the
field of fuel oil analysis). Its transmittance at 200 nm is relatively
low (0.60), but at 500 nm it goes up to 0.96-0.97 and stays at that
level until 9 µm, then it starts falling off (0.85 for 10 µm and
0.42 for 12 µm). Barium Fluoride is half as hard as Calcium Fluoride
and also more susceptible to thermal shock. It is somewhat more
expensive than Calcium Fluoride and not as readily available in large
sizes.
PRODUCTS
Phoenix Infrared offers BaF2 as blanks, generated parts, polished
optics, and coated optics. BaF2 optics include: optical windows,
lenses, and prisms, particularly when transmission into the
ultraviolet is desired.
Barium Fluoride is less resistant to attack by water than Calcium
Fluoride but attack does not begin until 500°C. In the dry atmosphere
Calcium Fluoride can be used up to 800°C. Barium Fluoride is the most
resistant fluoride to high energy radiation but does not have the VUV
transmission of other types.
Chemical Properties
|
BaF2
|
Crystal
Class
|
Cubic
|
Molecular
Weight
|
175.36
|
Lattice
Constant, Å
|
6.196
|
Density,
g/cm3 (20 °C)
|
4.89
|
Knoop
Hardness, kg/mm2
|
82
|
Young's
Modulus, GPa
|
53.05
|
Shear
Modulus, GPa
|
25.4
|
Bulk
Modulus, GPa
|
56.4
|
Apparent
Elastic Limit, MPa
|
26.89
|
Poisson
Ratio
|
0.343
|
Dielectric
Constant for 2 x 106 Hz
|
7.33
|
Melting
Temperature, K
|
1550
|
Specific
Heat, cal/(g K) at 274 K
|
0.096
|
Thermal
Conductivity, W/(m K) at 286 K
|
11.7
|
Thermal
Expansion, 1/K at 300 K
|
19.9
x 10-6
|
Bandgap,
eV
|
9.1
|
Solubility,
g/100 g H2O
|
0.17
|
Wavelength
µm
|
Refractive
Index
|
0.2
0.5
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
11.0
12.0
|
1.5573
1.4779
1.4686
1.4647
1.4612
1.4587
1.4511
1.4441
1.4357
1.4258
1.4144
1.4014
1.3865
1.3696
|
|